ESTUDIO DE LAS CONDICIONES DE PIRÓLISIS DEL RESIDUO DE EXTRACCIÓN DE BURITI
DOI:
https://doi.org/10.66104/k9c7j261Palabras clave:
Pirólisis; Biochar; Bio-aceite; Biomasa de Buriti; Degradación Térmica y Rendimiento.Resumen
Este estudio investigó la pirólisis de la biomasa de buriti con el objetivo de optimizar la producción de dos subproductos importantes: biochar y bio-aceite. Para este propósito, se realizaron experimentos en un reactor de pirólisis, variando las temperaturas entre 450 °C y 600 °C y los tiempos de proceso entre 10 y 60 minutos. El análisis termogravimétrico (TGA) reveló las diferentes etapas de la degradación térmica de la biomasa de buriti. Inicialmente, una pérdida de peso del 10% entre 10 °C y 200 °C se asoció con la evaporación del agua presente en la biomasa. Posteriormente, entre 200 °C y 400 °C, ocurrió una pérdida del 45%, correlacionada con la descomposición de hemicelulosa, celulosa y lignina, los principales componentes de la biomasa lignocelulósica. El mayor rendimiento de biochar se obtuvo a 450 °C durante 30 minutos de pirólisis (30,75%), mientras que el mayor rendimiento de bio-aceite se alcanzó a 525 °C durante 60 minutos (48,98%). El análisis de varianza (ANOVA) demostró que la temperatura influyó significativamente en el rendimiento de biochar, mientras que el tiempo fue el principal factor para el aumento del rendimiento de bio-aceite. El bio-aceite generado presentó un poder calorífico superior (PCS) de 10,68 MJ/kg, mientras que el biochar presentó un PCS significativamente mayor de 30,664 MJ kg-1, evidenciando su mayor eficiencia energética. El análisis espectroscópico por FTIR reveló la presencia de grupos funcionales como fenoles, alcoholes y compuestos alifáticos, confirmando la complejidad química de la biomasa. Los análisis de superficie ajustados, tanto en 3D como en 2D, indicaron que las temperaturas más bajas favorecen la producción de biochar, mientras que las temperaturas más altas y los tiempos más largos son más eficaces para la obtención de bio-aceite. Estos resultados sugieren que la pirólisis de la biomasa de buriti puede optimizarse para la producción eficiente de ambos subproductos, proporcionando una ruta sostenible para la valorización de esta biomasa.
Descargas
Referencias
ARAUJO, Rayanne O. et al. Renewable Energy from Biomass: an Overview of the Amazon Region. BioEnergy Research, v. 15, n. 2, p. 834–849, 16 jun. 2022. DOI: https://doi.org/10.1007/s12155-021-10308-x
BARBOZA, Natália L. et al. Buriti (Mauritia flexuosa L. f.): An Amazonian fruit with potential health benefits. Food Research International, v. 159, p. 111654, set. 2022. DOI: https://doi.org/10.1016/j.foodres.2022.111654
BATAGLION, Giovana Anceski et al. Bioactive Compounds of Buriti Fruit (Mauritia flexuosa L.f.). In: [S.l.: S.n.]. p. 411–436. DOI: https://doi.org/10.1007/978-3-030-30182-8_29
CARLOS DE SOUSA, Wallace; ALVES MORAIS, Romulo; DAMIAN GIRALDO ZUNIGA, Abraham. Buriti (Mauritia flexuosa) shell flour: Nutritional composition, chemical profile, and antioxidant potential as a strategy for valuing waste from native Brazilian fruits. Food Research International, v. 190, p. 114578, ago. 2024. DOI: https://doi.org/10.1016/j.foodres.2024.114578
CONSUMI, Marco et al. Analytical composition of flours through thermogravimetric and rheological combined methods. Thermochimica Acta, v. 711, p. 179204, maio 2022. DOI: https://doi.org/10.1016/j.tca.2022.179204
DA SILVA, Julie Brenda Santos et al. Buriti (Mauritia flexuosa L.) wastes as potential lignocellulosic feedstock for bioenergy production: Physicochemical properties, thermal behavior, and emission factors. Industrial Crops and Products, v. 206, p. 117689, dez. 2023. DOI: https://doi.org/10.1016/j.indcrop.2023.117689
FARIA, Douglas José; CARVALHO, Anna Paula Azevedo de; CONTE-JUNIOR, Carlos Adam. Fermentation of Biomass and Residues from Brazilian Agriculture for 2G Bioethanol Production. ACS Omega, v. 9, n. 39, p. 40298–40314, 1 out. 2024. DOI: https://doi.org/10.1021/acsomega.4c06579
FOONG, Shin Ying et al. Production of biochar from rice straw and its application for wastewater remediation − An overview. Bioresource Technology, v. 360, p. 127588, set. 2022. DOI: https://doi.org/10.1016/j.biortech.2022.127588
GONÇALVES, Maria Luiza M. B. B. et al. Valorization of Amazonian buriti (Mauritia flexuosa) semi-defatted residual cake as a circular economy strategy: A techno-economical analysis. Industrial Crops and Products, v. 226, p. 120629, abr. 2025. DOI: https://doi.org/10.1016/j.indcrop.2025.120629
GUO, Wei et al. Comparison of 17β-Estradiol Adsorption on Corn Straw- and Dewatered Sludge-Biochar in Aqueous Solutions. Molecules, v. 27, n. 8, p. 2567, 15 abr. 2022. DOI: https://doi.org/10.3390/molecules27082567
JANU, Rainer et al. Biochar surface functional groups as affected by biomass feedstock, biochar composition and pyrolysis temperature. Carbon Resources Conversion, v. 4, p. 36–46, 2021. DOI: https://doi.org/10.1016/j.crcon.2021.01.003
LIBORIO, Denisson O. et al. Evaluating black wattle bark industrial residue as a new feedstock for bioenergy via pyrolysis and multicomponent kinetic modeling. Renewable Energy, v. 228, p. 120693, jul. 2024. DOI: https://doi.org/10.1016/j.renene.2024.120693
LIU, Wu-Jun; JIANG, Hong; YU, Han-Qing. Emerging applications of biochar-based materials for energy storage and conversion. Energy & Environmental Science, v. 12, n. 6, p. 1751–1779, 2019. DOI: https://doi.org/10.1039/C9EE00206E
MAFRA, Edina Ruth Mendes Leal et al. Comparative analysis of seed biomass from Amazonian fruits for activated carbon production. Biomass Conversion and Biorefinery, v. 14, n. 10, p. 11279–11293, 5 maio 2024. DOI: https://doi.org/10.1007/s13399-022-03348-6
MD SALIM, Rafidah; ASIK, Jahimin; SARJADI, Mohd Sani. Chemical functional groups of extractives, cellulose and lignin extracted from native Leucaena leucocephala bark. Wood Science and Technology, v. 55, n. 2, p. 295–313, 23 mar. 2021. DOI: https://doi.org/10.1007/s00226-020-01258-2
MORAIS, Rômulo Alves et al. Nutritional Composition and Bioactive Compounds of Native Brazilian Fruits of the Arecaceae Family and Its Potential Applications for Health Promotion. Nutrients, v. 14, n. 19, p. 4009, 27 set. 2022. DOI: https://doi.org/10.3390/nu14194009
MUSTAPHA, Sherif Ishola et al. Biomass conversion for sustainable hydrogen generation: A comprehensive review. Fuel Processing Technology, v. 272, p. 108210, jul. 2025. DOI: https://doi.org/10.1016/j.fuproc.2025.108210
NEMET, Yara Karla de Salles. CARACTERIZAÇÃO DE BIOPRODUTOS DA PIRÓLISE DE BIOMASSA DE BARU (Dipteryx alata Vog) E SEU POTENCIAL COMO COADJUVANTES TECNOLÓGICOS. Dissertação—Palmas - TO: Universidade Federal do Tocantins, 8 maio 2020. DOI: https://doi.org/10.20873/uftv8-9984
SAHU, Sai Shankar; GHOSH, Dipita; MAITI, Subodh Kumar. Biochar for the Remediation of Heavy-Metal-Contaminated Soil: Present Scenario and Future Challenges. In: KAPOOR, Riti Thapar; SHAH, Maulin P. (Orgs.). Designer Biochar Assisted Bioremediation of Industrial Effluents; A Low-Cost Sustainable Green Technology. 1. ed. Boca Raton . FL: CRC Press, 2023. v. 1 p. 65–78. DOI: https://doi.org/10.1201/9781003203438-4
SALDARRIAGA, Juan F. et al. Fast characterization of biomass fuels by thermogravimetric analysis (TGA). Fuel, v. 140, p. 744–751, 15 jan. 2015. DOI: https://doi.org/10.1016/j.fuel.2014.10.024
WANG, Binhui et al. Pyrolysis behavior, kinetics, and thermodynamics of waste pharmaceutical blisters under CO2 atmosphere. Journal of Analytical and Applied Pyrolysis, v. 170, p. 105883, mar. 2023. DOI: https://doi.org/10.1016/j.jaap.2023.105883
WANG, Guanyu et al. A Review of Recent Advances in Biomass Pyrolysis. Energy & Fuels, v. 34, n. 12, p. 15557–15578, 17 dez. 2020. DOI: https://doi.org/10.1021/acs.energyfuels.0c03107
WANG, Wenli et al. Current Challenges and Perspectives for the Catalytic Pyrolysis of Lignocellulosic Biomass to High-Value Products. Catalysts, v. 12, n. 12, p. 1524, 26 nov. 2022. DOI: https://doi.org/10.3390/catal12121524
YAO, Zhitong et al. Thermochemical conversion of waste printed circuit boards: Thermal behavior, reaction kinetics, pollutant evolution and corresponding controlling strategies. Progress in Energy and Combustion Science, v. 97, p. 101086, jul. 2023. DOI: https://doi.org/10.1016/j.pecs.2023.101086
Descargas
Publicado
Número
Sección
Licencia
Derechos de autor 2026 Natália de Diniz Martins , Schaline Winck Alberti, Edson Antonio da Silva, Plínio Ribeiro Fajardo Campos
Esta obra está bajo una licencia internacional Creative Commons Atribución 4.0.
Authors who publish in this journal agree to the following terms:
Authors retain copyright and grant the journal the right of first publication, with the work simultaneously licensed under the Creative Commons Attribution License, which permits the sharing of the work with proper acknowledgment of authorship and initial publication in this journal;
Authors are authorized to enter into separate, additional agreements for the non-exclusive distribution of the version of the work published in this journal (e.g., posting in an institutional repository or publishing it as a book chapter), provided that authorship and initial publication in this journal are properly acknowledged, and that the work is adapted to the template of the respective repository;
Authors are permitted and encouraged to post and distribute their work online (e.g., in institutional repositories or on their personal websites) at any point before or during the editorial process, as this may lead to productive exchanges and increase the impact and citation of the published work (see The Effect of Open Access);
Authors are responsible for correctly providing their personal information, including name, keywords, abstracts, and other relevant data, thereby defining how they wish to be cited. The journal’s editorial board is not responsible for any errors or inconsistencies in these records.
PRIVACY POLICY
The names and email addresses provided to this journal will be used exclusively for the purposes of this publication and will not be made available for any other purpose or to third parties.
Note: All content of the work is the sole responsibility of the author and the advisor.
