DUMP HEAP LEACHING SYSTEMS: ENGINEERING DESIGN, HYDRODYNAMICS, ENVIRONMENTAL CONTROL, AND INDUSTRIAL APPLICATIONS
DOI:
https://doi.org/10.66104/4w2dd058Palabras clave:
Dump leaching; Heap leaching; Percolation leaching; Hydrometallurgy; Low-grade ores; Mine waste processingResumen
Dump leaching remains one of the earliest and most cost-effective hydrometallurgical methods for extracting metals from low-grade ores and mine waste; however, its industrial relevance is increasingly limited by fundamental issues in fluid dynamics, metallurgical efficiency, and environmental impact. This review critically assesses the engineering design, fluid flow behavior, and leaching chemistry shaping dump leaching systems, with emphasis on how heterogeneity, preferential flow, and poor solution distribution affect recovery efficiency. While traditional operations report metal recoveries generally below those achieved in modern heap leaching systems, recent innovations—including bioleaching integration, geotechnical monitoring, and reprocessing of old dumps—have partly reduced these limitations. The analysis points out that the main obstacle is not just leaching kinetics but the interaction between hydraulic movement and reactive interfaces within large, unstructured ore masses. Additionally, environmental concerns like acid drainage and groundwater pollution remain key barriers to sustainable use. The review suggests that dump leaching should not stand alone as a future technology but rather serve as a transitional or supplementary method combined with controlled heap leaching and advanced monitoring to enhance recovery and environmental safety.
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1. Aachhera, S. (2026). Bridging the bottlenecks in biohydrometallurgy: Enhancing kinetics, resource utilization, and sustainability for scalable metal recovery. E3S Web of Conferences, 693, 02001. https://doi.org/10.1051/e3sconf/202669302001 DOI: https://doi.org/10.1051/e3sconf/202669302001
2. Ahn, J. (2020). Investigation of chalcopyrite leaching kinetics by alternative leaching chemicals (Doctoral dissertation, University of Arizona).
3. Arpalahti, A. (2021). Heap leaching of nickel sulfide ore (Doctoral dissertation, Aalto University). Aalto University publication series Doctoral Dissertations, 115/2021. Retrieved January 8, 2026, from https://aaltodoc.aalto.fi/items/2d2b17c5-f789-492f-9131-f154c5da3cc4
4. Battur, M. (2021). Geometallurgical study of copper whole ore from an open pit mine with various leaching systems (Master’s thesis, The University of Arizona). ProQuest Dissertations & Theses Global. Retrieved April 8, 2026, from https://www.proquest.com/openview/9fa1ceeaafe7db2c992e92df13cc1017
5. Bárzaga-Martell, L., Diaz-Quezada, S., Estay, H., & Ruiz-del-Solar, J. (2025). Estimation of copper grade, acid consumption, and moisture content in heap leaching using extended and unscented Kalman filters. Minerals, 15(5), 521. https://doi.org/10.3390/min15050521. DOI: https://doi.org/10.3390/min15050521
6. Benzal, E., Cano, A., Solé, M. et al. Copper Recovery from PCBs by Acidithiobacillus ferrooxidans: Toxicity of Bioleached Metals on Biological Activity. Waste Biomass Valor 11, 5483–5492 (2020). https://doi.org/10.1007/s12649-020-01036-y. DOI: https://doi.org/10.1007/s12649-020-01036-y
7. Bhatti, T. M., & Tuovinen, O. H. (2023). Some historical briefs and outlooks of the chemical and biological acid leaching of uranium ores. The Nucleus. DOI: https://doi.org/10.71330/nucleus.60.01.1274
8. Bhatti, T. M., Haq, N., & Siddiqui, R. H. (2024). Bioleaching of copper from sulfide ores: A short review. Geologica, 8, Article 2, 45–70. https://geologica.gov.pk/.
9. Binnemans, K., Jones, P.T. The Twelve Principles of Circular Hydrometallurgy. J. Sustain. Metall. 9, 1–25 (2023). https://doi.org/10.1007/s40831-022-00636-3. DOI: https://doi.org/10.1007/s40831-022-00636-3
10. Bridge, G. (1999). The decommissioning of leach dumps and protection of water quality: Lessons for best practice from copper and gold leaching operations in the United States. In Environmental policy in mining (1st ed.). https://doi.org/10.1201/9780203756966-9. DOI: https://doi.org/10.1201/9780203756966-9
11. Brown, M. J., & Moses, V. (2020). Metal recovery and processing. In Biotechnology: The science and the business. DOI: https://doi.org/10.1201/9781003078432-30
12. Bruce, E., Sepúlveda, R., Castillo, J., & Saldaña, M. (2024). Effect of incorporation of sulfation in columnar modeling of oxidized copper minerals on predictions of leaching kinetics. Metals, 14(6), 708. https://doi.org/10.3390/met14060708. DOI: https://doi.org/10.3390/met14060708
13. Bryan, C.G., Harrison, S.T.L. (2023). Microbial Ecology of Bioheaps, Stirred Tanks, and Mine Wastes. In: Johnson, D.B., Bryan, C.G., Schlömann, M., Roberto, F.F. (eds) Biomining Technologies. Springer, Cham. https://doi.org/10.1007/978-3-031-05382-5_7. DOI: https://doi.org/10.1007/978-3-031-05382-5_7
14. Chamberlin, P. D. (2020). In situ leaching. In SME mining engineering handbook (2nd ed.). Society for Mining, Metallurgy & Exploration..
15. Chattopadhyay, S., Chattopadhyay, D. (2020). Coal and Other Mining Operations: Role of Sustainability. In: Malhotra, R. (eds) Fossil Energy. Encyclopedia of Sustainability Science and Technology Series. Springer, New York, NY. https://doi.org/10.1007/978-1-4939-9763-3_864. DOI: https://doi.org/10.1007/978-1-4939-9763-3_864
16. Cheru, M. S. (2021). Bio hydrometallurgical technology, application and process enhancement. In M. K. Nazal & H. Zhao (Eds.), Heavy metals: Their environmental impacts and mitigation. IntechOpen. https://doi.org/10.5772/intechopen.94206. DOI: https://doi.org/10.5772/intechopen.94206
17. Cozma, P., Bețianu, C., Hlihor, R.-M., Simion, I. M., & Gavrilescu, M. (2024). Bio-recovery of metals through biomining within circularity-based solutions. Processes, 12(9), 1793. https://doi.org/10.3390/pr12091793. DOI: https://doi.org/10.3390/pr12091793
18. Dash, J., Ojha, R. & Pradhan, D. Progress in bioleaching and its mechanism: a short review. Discov Environ 3, 238 (2025). https://doi.org/10.1007/s44274-025-00454-w. DOI: https://doi.org/10.1007/s44274-025-00454-w
19. Devi, A., & Ganesh, S. (2023). Recent bioleaching approaches employed for the extraction of metals in mining fields for the purpose of utilization and creating the sustainable future. Total Quality Management & Business Excellence. https://doi.org/10.1002/tqem.22085. DOI: https://doi.org/10.1002/tqem.22085
20. Dixon, D.G., Lizama, H.M. (2023). Design, Construction, and Modelling of Bioheaps. In: Johnson, D.B., Bryan, C.G., Schlömann, M., Roberto, F.F. (eds) Biomining Technologies. Springer, Cham. https://doi.org/10.1007/978-3-031-05382-5_2. DOI: https://doi.org/10.1007/978-3-031-05382-5_2
21. Dreier, J. E. (2025). Management of copper heap leach projects: A geologist’s perspective. In Society of Economic Geologists Special Publication. Society of Economic Geologists. https://doi.org/10.5382/COM.16.24. DOI: https://doi.org/10.5382/COM.16.24
22. Estay, H., Díaz-Quezada, S. Deconstructing the Leaching Ratio. Mining, Metallurgy & Exploration 37, 1329–1337 (2020). https://doi.org/10.1007/s42461-020-00243-4. DOI: https://doi.org/10.1007/s42461-020-00243-4
23. Estay, H., Díaz-Quezada, S., Arancibia, E. et al. Economic Assessment of an In Situ Leaching Operation with Ore Preconditioning Using Sublevel Stoping Techniques. Mining, Metallurgy & Exploration 40, 493–504 (2023). https://doi.org/10.1007/s42461-023-00736-y. DOI: https://doi.org/10.1007/s42461-023-00736-y
24. Ferrer Cardona, V. A. (2020). Industrial upscaling feasibility assessment and identification of key performance indicators for an in-situ bio-leaching project in narrow vein sulfide ores (Master’s thesis, Politecnico di Torino). Retrieved April 8, 2026, from https://webthesis.biblio.polito.it/14742/
25. Free, M. L. (2021). Metal extraction. In Hydrometallurgy: Fundamentals and applications. Springer. DOI: https://doi.org/10.1007/978-3-030-88087-3_5
26. Free, M. L. (2024). Principles of biohydrometallurgy. In Treatise on process metallurgy (2nd ed., Vol. 3: Industrial processes, pp. 507–514). Elsevier. https://doi.org/10.1016/B978-0-323-85373-6.00025-9. DOI: https://doi.org/10.1016/B978-0-323-85373-6.00025-9
27. Fukano, Y., & Miura, A. (2021). Chalcopyrite leaching with iodine (JX iodine process) for various ore types. Hydrometallurgy, 206, 105752. https://doi.org/10.1016/j.hydromet.2021.105752 DOI: https://doi.org/10.1016/j.hydromet.2021.105752
28. Funari, V., Toller, S., Vitale, L. et al. Urban mining of municipal solid waste incineration (MSWI) residues with emphasis on bioleaching technologies: a critical review. Environ Sci Pollut Res 30, 59128–59150 (2023). https://doi.org/10.1007/s11356-023-26790-z. DOI: https://doi.org/10.1007/s11356-023-26790-z
29. Gantulga, S., Tsend-Ayush, T., Altantuyaa, B., et al. (2025). Pilot tests for processing oxidized copper ores from the Erdenetiin Ovoo deposit using heap leaching. Izvestiya. Non-Ferrous Metallurgy.
30. Georgiev, P. S., Nicolova, M., Spasova, I., Iliev, M., & Ilieva, R. (2025). Biological leaching of copper, zinc, and cobalt from pyrometallurgical copper slags using Aspergillus niger and Penicillium ochrochloron. Journal of Ecological Engineering, 26(12), 197–213. https://doi.org/10.12911/22998993/208320. DOI: https://doi.org/10.12911/22998993/208320
31. Guo, Y., Li, X., Li, Q. et al. Environmental impact assessment of acidic coal gangue leaching solution on groundwater: a coal gangue pile in Shanxi, China. Environ Geochem Health 46, 120 (2024). https://doi.org/10.1007/s10653-024-01861-3. DOI: https://doi.org/10.1007/s10653-024-01861-3
32. Harichandan, B., & Mandre, N. R. (2021). Studies on the potential recovery of copper from low-grade mixed sulfide-oxide ore and optimization of the process parameters. Separation Science and Technology. https://doi.org/10.1080/01496395.2021.1933036. DOI: https://doi.org/10.1080/01496395.2021.1933036
33. Jia, Y., Ruan, R., Qu, J., Tan, Q., Sun, H., & Niu, X. (2024). Multi-scale and trans-disciplinary research and technology developments of heap bioleaching. Minerals, 14(8), 808. https://doi.org/10.3390/min14080808. DOI: https://doi.org/10.3390/min14080808
34. Johnson, D.B., Roberto, F.F. (2023). Evolution and Current Status of Mineral Bioprocessing Technologies. In: Johnson, D.B., Bryan, C.G., Schlömann, M., Roberto, F.F. (eds) Biomining Technologies. Springer, Cham. https://doi.org/10.1007/978-3-031-05382-5_1. DOI: https://doi.org/10.1007/978-3-031-05382-5_1
35. Kamalesh, A. K. (2022). Efficient extraction of valuable metals from polymetallic shale using leaching and adsorption techniques (Master’s thesis, University of Calgary). Retrieved April 8, 2026, from http://hdl.handle.net/1880/114639.
36. Keke, M., Nnanwube, I. A., & Onukwuli, O. D. (2023). Overview of bioleaching. Journal of Engineering Research and Reports, 25(2), 108–129. https://doi.org/10.9734/jerr/2023/v25i2884. DOI: https://doi.org/10.9734/jerr/2023/v25i2884
37. Kiegiel, K., Roubinek, O., Gajda, D., Kalbarczyk, P., Zakrzewska-Kołtuniewicz, G., & Chmielewski, A. G. (2021). Studies on uranium recovery from a U-bearing Radoniów dump. Nukleonika, 66(4), 115–119. https://doi.org/10.2478/nuka-2021-0017. DOI: https://doi.org/10.2478/nuka-2021-0017
38. Kiprono, N. R., Smoliński, T., Rogowski, M., Herdzik-Koniecko, I., Sudlitz, M., & Chmielewski, A. G. (2024). Kenya’s mineral landscape: A review of the mining status and potential recovery of strategic and critical metals through hydrometallurgical and flotation techniques. Minerals, 14(1), 21. https://doi.org/10.3390/min14010021. DOI: https://doi.org/10.3390/min14010021
39. Kinyua, E. M., Jianhua, Z., Kasomo, R. M., Mauti, D., & Mwangangi, J. (2022). A review of the influence of blast fragmentation on downstream processing of metal ores. Minerals Engineering, 186, 107743. https://doi.org/10.1016/j.mineng.2022.107743. DOI: https://doi.org/10.1016/j.mineng.2022.107743
40. Koizumi, J. (2020). Genetically engineered microorganisms exploitation for biocleaning of coal: A countermeasure to acid rain. In Recombinant microbes for industrial and agricultural applications. Taylor & Francis. DOI: https://doi.org/10.1201/9781003067191-51
41. Kour, G., Kothari, R., Mohan Singh, H. et al. Microbial leaching for valuable metals harvesting: versatility for the bioeconomy. Environmental Sustainability 4, 215–229 (2021). https://doi.org/10.1007/s42398-020-00143-9. DOI: https://doi.org/10.1007/s42398-020-00143-9
42. Krook, J., Carvalho, T., Cleall, P. J., & Rosendal, R. (2020). Recovery technologies for materials in landfills. European Cooperation in Science and Technology (COST). https://doi.org/10.5281/zenodo.3768960.
43. Kumar S P. & Yaashikaa, P. R. (2020). Recent trends and challenges in bioleaching technologies. In Biovalorisation of wastes to renewable chemicals and biofuels (pp. 373–388). Elsevier. https://doi.org/10.1016/B978-0-12-817951-2.00020-1. DOI: https://doi.org/10.1016/B978-0-12-817951-2.00020-1
44. Lee, J., Pearlman, J., Callisaya, S., Ahn, J., Kim, J. (2025). Copper Extraction from Chalcopyrite with New Hydrometallurgical Systems. In: 12th International Copper Conference. COPR 2025. Springer, Cham. https://doi.org/10.1007/978-3-032-00102-3_59. DOI: https://doi.org/10.1007/978-3-032-00102-3_59
45. Li, J., Yang, H., Tong, L., & Sand, W. (2021). Some aspects of industrial heap bioleaching technology: From basics to practice. Mineral Processing and Extractive Metallurgy Review, 43(4), 1–19. https://doi.org/10.1080/08827508.2021.1893720. DOI: https://doi.org/10.1080/08827508.2021.1893720
46. Li, Q., Yang, Y., Ma, J., Sun, J., Li, G., Zhang, R., Cui, Z., Li, T., & Liu, X. (2023). Sulfur enhancement effects for uranium bioleaching in column reactors from a refractory uranium ore. Frontiers in Microbiology, 14, 1107649. https://doi.org/10.3389/fmicb.2023.1107649 DOI: https://doi.org/10.3389/fmicb.2023.1107649
47. .Litvinov, V.V., Aitekenova, D.A., Zhuravlev, I.P. et al. Increasing the Duration of Dump Leaching of Copper Under Winter Conditions. Metallurgist 67, 542–553 (2023). https://doi.org/10.1007/s11015-023-01536-x. DOI: https://doi.org/10.1007/s11015-023-01536-x
48. Lizama, H. M. (2021). How copper dump leaching works. Minerals Engineering, 171, 107075. https://doi.org/10.1016/j.mineng.2021.107075. DOI: https://doi.org/10.1016/j.mineng.2021.107075
49. Ma, L., Huang, C., Liu, ZS. et al. A Full-Scale Case Study on the Leaching Process of Acid Rock Drainage in Waste Rock Piles and the Net Infiltration Through Cover Systems. Water Air Soil Pollut 231, 305 (2020). https://doi.org/10.1007/s11270-020-04660-5. DOI: https://doi.org/10.1007/s11270-020-04660-5
50. Maghsoudy, S., Bakhtiari, O., & Maghsoudy, S. (2022). Tortuosity prediction and investigation of fluid flow behavior using pore flow approach in heap leaching. Hydrometallurgy, 211, 105868. https://doi.org/10.1016/j.hydromet.2022.105868. DOI: https://doi.org/10.1016/j.hydromet.2022.105868
51. Mahmood, S., Naz, G., Sarwar, A., Hussain, F., Kalsoom, R., Mumtaz, F., Abdullah, A., Sultana, S., & Akram, M. (2025). Bioleaching process for the recovery of metals: A review. Pakistan Journal of Medical & Cardiological Review, 4(4). https://doi.org/10.64105/21t9m737.
52. Mills, A. L. (1985). Acid mine waste drainage: Microbial impact on the recovery of soil and water ecosystems. In Soil reclamation processes: Microbiological analyses and applications. CRC Press. https://doi.org/10.1201/9781003065340-2.
53. Mitshiabo, M. E., & Sole, K. C. (2023). Effect of LixTRA 118 leaching aid on heap leaching of copper ores—Column study. In Proceedings of Copper–Cobalt 2023 Conference. Southern African Institute of Mining and Metallurgy (SAIMM). Retrieved April 8, 2026, from https://www.saimm.co.za/Conferences/Copper-Cobalt-2023/25-Mitshiabu-251-262.pdf
54. Mokmeli, M. (2020). Pre-feasibility study in hydrometallurgical treatment of low-grade chalcopyrite ores from Sarcheshmeh copper mine. Hydrometallurgy, 191, 105215. https://doi.org/10.1016/j.hydromet.2019.105215 DOI: https://doi.org/10.1016/j.hydromet.2019.105215
55. Moravvej, Z., Mohebbi, A., Vakylabad, A. B., & Raeissi, S. (2021). The effect of radio-waves irradiation on copper-ore leaching. Hydrometallurgy, 201, 105584. https://doi.org/10.1016/j.hydromet.2021.105584. DOI: https://doi.org/10.1016/j.hydromet.2021.105584
56. Muravyov, M., & Panyushkina, A. (2023). Comparison of sphalerite, djurleite, and chalcopyrite leaching by chemically and biologically generated ferric sulfate solutions. Hydrometallurgy, 219, 106067. https://doi.org/10.1016/j.hydromet.2023.106067. DOI: https://doi.org/10.1016/j.hydromet.2023.106067
57. Neira, A., Pizarro, D., Quezada, V., & Velásquez-Yévenes, L. (2021). Pretreatment of copper sulphide ores prior to heap leaching: A review. Metals, 11(7), 1067. https://doi.org/10.3390/met11071067. DOI: https://doi.org/10.3390/met11071067
58. Nkuna, R., Ijoma, G. N., Matambo, T. S., & Chimwani, N. (2022). Accessing metals from low-grade ores and the environmental impact considerations: A review of the perspectives of conventional versus bioleaching strategies. Minerals, 12(5), 506. https://doi.org/10.3390/min12050506. DOI: https://doi.org/10.3390/min12050506
59. Odidi, M. D., Fagan-Endres, M. A., & Harrison, S. T. L. (2023). Moisture absorption rates via capillary suction within packed beds—The effect of material and fluid properties with implications for heap leaching operations. Hydrometallurgy, 215, 105975. https://doi.org/10.1016/j.hydromet.2022.105975. DOI: https://doi.org/10.1016/j.hydromet.2022.105975
60. Odidi, M. D., Fagan-Endres, M. A., & Harrison, S. T. L. (2023). Residence time distribution analysis of drip-irrigated beds—The effect of material and fluid properties with implications for heap leaching practice. Minerals, 13(2), 267. https://doi.org/10.3390/min13020267. DOI: https://doi.org/10.3390/min13020267
61. Ouassel, S., Guettaf, H., Khemaissia, S. et al. Parametric study of uranium ore acid leaching by percolation: experimental design, kinetic study and numerical modeling with the unreacted shrinking core model. J Radioanal Nucl Chem 334, 3599–3612 (2025). https://doi.org/10.1007/s10967-025-10070-w. DOI: https://doi.org/10.1007/s10967-025-10070-w
62. Page, M. J., McKenzie, J. E., Bossuyt, P. M., Boutron, I., Hoffmann, T. C., Mulrow, C. D., Shamseer, L., Tetzlaff, J. M., Akl, E. A., Brennan, S. E., Chou, R., Glanville, J., Grimshaw, J. M., Hróbjartsson, A., Lalu, M. M., Li, T., Loder, E. W., Mayo-Wilson, E., McDonald, S., McGuinness, L. A., Stewart, L. A., Thomas, J., Tricco, A. C., Welch, V. A., Whiting, P., & Moher, D. (2021). The PRISMA 2020 statement: An updated guideline for reporting systematic reviews. BMJ. DOI: https://doi.org/10.1136/bmj.n71
63. Pattanaik, A., Samal, D. K., Sukla, L. B., et al. (2020). Advancements and use of omic technologies in the field of bioleaching: A review. Biointerface Research in Applied Chemistry.
64. Peng, Z., Fu, X., Pan, Z., Gao, Y., He, D., Fan, X., Yue, T., & Sun, W. (2022). Efficient recovery of the combined copper resources from copper oxide bearing limonite ore by magnetic separation and leaching technology. Minerals, 12(10), 1258. https://doi.org/10.3390/min12101258 DOI: https://doi.org/10.3390/min12101258
65. Pereira, A. C. (2026a). From columns to industrial heaps: Critical design considerations for heap leach pilot plants. International Journal of Current Science Research and Review. https://doi.org/10.5281/zenodo.18979542
66. Pereira, A. C. (2026b). Vat leaching and box leaching in hydrometallurgy: Process principles, industrial applications, and future perspectives. International Journal of Modern Research in Engineering and Technology. https://doi.org/10.47191/ijcsrr/V9-i3-42 DOI: https://doi.org/10.47191/ijcsrr/V9-i3-42
67. Ren, Z., Krishnamoorthy, P., Zuñiga Sanchez, P., Asselin, E., Dixon, D. G., & Mora, N. (2020). Catalytic effect of ethylene thiourea on the leaching of chalcopyrite. Hydrometallurgy, 196, 105410. https://doi.org/10.1016/j.hydromet.2020.105410. DOI: https://doi.org/10.1016/j.hydromet.2020.105410
68. Roberto, F.F., Schippers, A. Progress in bioleaching: part B, applications of microbial processes by the minerals industries. Appl Microbiol Biotechnol 106, 5913–5928 (2022). https://doi.org/10.1007/s00253-022-12085-9. DOI: https://doi.org/10.1007/s00253-022-12085-9
69. Robertson, S. W., van Staden, P. J., Cherkaev, A., & Petersen, J. (2022). Properties governing the flow of solution through crushed ore for heap leaching. Hydrometallurgy, 208, 105811. https://doi.org/10.1016/j.hydromet.2021.105811 DOI: https://doi.org/10.1016/j.hydromet.2021.105811
70. Robertson, S. W., Basson, P., van Staden, P. J., & Petersen, J. (2023). Properties governing flow of solution and air through crushed ore for heap leaching: Part II unsaturated dual-phase flow. Hydrometallurgy, 215, 105990. https://doi.org/10.1016/j.hydromet.2022.105990 DOI: https://doi.org/10.1016/j.hydromet.2022.105990
71. Robertson, S. W., & Petersen, J. (2024). Modelling unsaturated dual-phase flow through crushed ores for heap leaching. Journal of the Southern African Institute of Mining and Metallurgy, 124(12). https://doi.org/10.17159/2411-9717/697/2024 DOI: https://doi.org/10.17159/2411-9717/697/2024
72. Saldaña, M., Gálvez, E., Robles, P., Castillo, J., & Toro, N. (2022a). Copper mineral leaching mathematical models—A review. Materials, 15(5), 1757. https://doi.org/10.3390/ma15051757. DOI: https://doi.org/10.3390/ma15051757
73. Saldaña, M., Jeldres, M., Galleguillos Madrid, F. M., Gallegos, S., Salazar, I., Robles, P., & Toro, N. (2023). Bioleaching modeling—A review. Materials, 16(10), 3812. https://doi.org/10.3390/ma16103812. DOI: https://doi.org/10.3390/ma16103812
74. Saldaña, M., Neira, P., Gallegos, S., Salinas-Rodríguez, E., Pérez-Rey, I., & Toro, N. (2022b). Mineral leaching modeling through machine learning algorithms—A review. Frontiers in Earth Science, 10, 816751. https://doi.org/10.3389/feart.2022.816751. DOI: https://doi.org/10.3389/feart.2022.816751
75. Salinas-Farran, L., Brownscombe, W., Iacoviello, F., Shearing, P. R., Brito-Parada, P., & Neethling, S. J. (2024). The impact of chloride ions on chalcopyrite leaching: A multiscale and multimodal assessment. Minerals Engineering, 213, 108762. https://doi.org/10.1016/j.mineng.2024.108762 DOI: https://doi.org/10.1016/j.mineng.2024.108762
76. .Schlesinger, M. E., Sole, K. C., Davenport, W. G., & Alvear Flores, G. R. F. (2021). Extractive metallurgy of copper (6th ed.). Elsevier. https://doi.org/10.1016/C2019-0-03265-7. DOI: https://doi.org/10.1016/C2019-0-03265-7
77. Shamsuddin, M., & Sohn, H. Y. (2023). Role of electrochemical processes in the extraction of metals and alloys—A review. Mineral Processing and Extractive Metallurgy. https://doi.org/10.1080/25726641.2023.2255368. DOI: https://doi.org/10.1080/25726641.2023.2255368
78. Sobral, L., & Oliveira, D. M. de. (2016). The influence of different mineral processing techniques on the bioextraction of metal values from ores and secondary sources. CETEM—Centre for Mineral Technology. Retrieved April 8, 2026, from https://www.cetem.gov.br/antigo/images/congressos/2016/CAC0069-00-16.pdf.
79. Sole, K.C., McCullum, T., Nisbett, A., Steeples, J., Huang, D. (2025). Copper Solvent Extraction: 2025 Global Survey of Operating Practice and Performance. In: 12th International Copper Conference. COPR 2025. Springer, Cham. https://doi.org/10.1007/978-3-032-00102-3_55. DOI: https://doi.org/10.1007/978-3-032-00102-3_55
80. Szymanowski, J. (1993). Hydroxyoximes and copper hydrometallurgy. Routledge. https://doi.org/10.1201/9780203751336. DOI: https://doi.org/10.1201/9780203751336
81. Tang, M., & Esmaeili, K. (2021). Heap leach pad surface moisture monitoring using drone-based aerial images and convolutional neural networks: A case study at the El Gallo Mine, Mexico. Remote Sensing, 13(8), 1420. https://doi.org/10.3390/rs13081420. DOI: https://doi.org/10.3390/rs13081420
82. Tezyapar Kara, I., Kremser, K., Wagland, S.T. et al. Bioleaching metal-bearing wastes and by-products for resource recovery: a review. Environ Chem Lett 21, 3329–3350 (2023). https://doi.org/10.1007/s10311-023-01611-4. DOI: https://doi.org/10.1007/s10311-023-01611-4
83. Thacker, S., Tipre, D. R., & Dave, S. (2023). Biohydrometallurgical metal recycling/recovery from e-waste: Current trend, challenges, and future perspective. In Management of electronic waste (pp. 436–464). Wiley. https://doi.org/10.1002/9781119894360.ch17 DOI: https://doi.org/10.1002/9781119894360.ch17
84. Thiyagarajulu, N., Yuvaraj, D., Gopinathan, P., Deepak, P., et al. (2025). Assessment on sustainable biomining: Integrating environmental responsibility and economic viability. Land Degradation & Development, 37(1), 3–27. https://doi.org/10.1002/ldr.70107 DOI: https://doi.org/10.1002/ldr.70107
85. Tiwari, S., Aachhera, S., Verma, P., Gahan, C.S. (2025). Bioremediation of E-Waste: A Sustainable Approach. In: Verma, P. (eds) Biotechnology for Environmental Sustainability. Interdisciplinary Biotechnological Advances. Springer, Singapore. https://doi.org/10.1007/978-981-97-7221-6_25. DOI: https://doi.org/10.1007/978-981-97-7221-6_25
86. Togtokhbaatar, P.-O. (2022). Leaching of copper and gold concentrate in the presence of halides (Doctoral dissertation). Retrieved April 8, 2026, from https://nbn-resolving.org/urn:nbn:de:bsz:105-qucosa2-819041.
87. Vargas, T., Estay, H., Arancibia, E., & Díaz-Quezada, S. (2020). In situ recovery of copper sulfide ores: Alternative process schemes for bioleaching application. Hydrometallurgy, 196, 105442. https://doi.org/10.1016/j.hydromet.2020.105442. DOI: https://doi.org/10.1016/j.hydromet.2020.105442
88. Velásquez-Yévenes, L., Malverde, S., & Quezada, V. (2022). A sustainable bioleaching of a low-grade chalcopyrite ore. Minerals, 12(4), 487. https://doi.org/10.3390/min12040487. DOI: https://doi.org/10.3390/min12040487
89. Véliz, M., Videla Leiva, A., & Martínez Bellange, P. (2023). Copper bioleaching operations in Chile: Towards new challenges and developments. In D. B. Johnson, C. G. Bryan, M. Schlömann, & F. F. Roberto (Eds.), Biomining technologies. Springer. https://doi.org/10.1007/978-3-031-05382-5_9 DOI: https://doi.org/10.1007/978-3-031-05382-5_9
90. Wang, L, Yin, S. (Eds.). (2023). Current status of low-grade minerals and mine wastes recovery: Reaction mechanism, mass transfer, and process control. MDPI. https://doi.org/10.3390/books978-3-0365-7970-2 DOI: https://doi.org/10.3390/books978-3-0365-7970-2
91. .Wang, L., Yin, S., Wu, A., & Chen, W. (2020). Effect of stratified stacks on extraction and surface morphology of copper sulfides. Hydrometallurgy, 191, 105226. https://doi.org/10.1016/j.hydromet.2019.105226. DOI: https://doi.org/10.1016/j.hydromet.2019.105226
92. Wang, L., Yin, S., Zhang, X., Yan, Z., & Liao, W. (2022). Hydrodynamic hysteresis and solute transport in agglomerated heaps under irrigation, stacking, and bioleaching controlling. Minerals, 12(12), 1623. https://doi.org/10.3390/min12121623. DOI: https://doi.org/10.3390/min12121623
93. Wang, L., Zhang, X., Yin, S., Zhang, X., Liu, P., & Ilankoon, I. M. S. K. (2023). Three-dimensional characterisation of pore networks and fluid flow in segregated heaps in the presence of crushed ore and agglomerates. Hydrometallurgy, 219, 106082. https://doi.org/10.1016/j.hydromet.2023.106082. DOI: https://doi.org/10.1016/j.hydromet.2023.106082
94. Warhurst, A. (2024). Mining, mineral processing, and extractive metallurgy: An overview of the technologies and their impact on the physical environment. In A. Warhurst & M. L. Noronha (Eds.), Environmental policy in mining: Corporate strategy and planning. Taylor & Franci.
95. Yilmaz, S., Sirkeci, A. A., Bilen, M., & Kizgut, S. (2020). Increasing the heap leach efficiency of Uşak Kışladağ gold ore using nut shell as permeability aid. Hydrometallurgy, 198, 105520. https://doi.org/10.1016/j.hydromet.2020.105520. DOI: https://doi.org/10.1016/j.hydromet.2020.105520
96. Zhang, M. (2023). Engineering Design and Process Requirements. In: Iron Ores Bioprocessing. Springer, Cham. https://doi.org/10.1007/978-3-031-10102-1_5. DOI: https://doi.org/10.1007/978-3-031-10102-1_5
97. Zhan, R.-T., Zhang, H.-B., Pei, J.-N., Yang, H., et al. (2025). Recent advances in recycling of copper-based waste materials: A critical review. cMat, 2(2). https://doi.org/10.1002/cmt2.70005. DOI: https://doi.org/10.1002/cmt2.70005
98. Zheng, Q. (2026). X-ray imaging of fluid flow and reactive transport in dual-porosity media: Implications for heap leaching (Doctoral dissertation, University of New South Wales).
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