MINERAL AND TECHNOLOGICAL CHARACTERIZATION OF PHOSPHATE TAILINGS FOR POSSIBLE REPROCESSING OF ENVIRONMENTAL LIABILITIES
DOI:
https://doi.org/10.66104/pep5m473Keywords:
Mineral Characterization, Waste Reuse, Mining TailingsAbstract
This study investigates the mineralogical and technological characterization of a phosphate mining tailing, with the objective of evaluating its reprocessing feasibility. The increasing generation of mining waste and the need for higher phosphorus recovery make it essential to explore alternatives for reutilizing such materials. The analyzed tailing, originating from desliming stages of the beneficiation process, exhibits predominantly ultrafine particle size distribution, with approximately 50% of particles smaller than 0.012 mm. Chemical analysis indicated an average P₂O₅ grade of 7%, with the highest concentrations occurring in the particle-size range between 0.011 and 0.044 mm. The tailing’s mineralogy is predominantly composed of apatite, magnetite, micas, and clay minerals, all of which hinder conventional concentration processes. Pure apatite collected for complementary studies exhibited electrokinetic behavior compatible with the use of anionic collectors, such as fatty acids, at pH values above 8.5. However, the presence of contaminants and the ultrafine particle size indicate low flotation efficiency under conventional conditions. Therefore, effective reprocessing of the tailing requires advanced mineral beneficiation routes, such as selective aggregation and leaching, reinforcing the need for modern technologies for handling discarded residues to ensure more sustainable, safe, and efficient mining operations.
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References
AHMED, N.; JAMESON, G. J. Flotation kinetics. Mineral processing and extractive metallurgy review, p. 77–99, 1989. DOI: https://doi.org/10.1080/08827508908952645
BANIHASHEMI, Seyed Ramin et al. Selective nitric acid leaching of rare-earth elements from calcium and phosphate in fluorapatite concentrate. JOM (Warrendale, Pa.: 1989), v. 71, n. 12, p. 4578–4587, 2019. DOI: https://doi.org/10.1007/s11837-019-03605-6
BARROS, Luiz Antonio Fonseca de. Flotação da apatita da Jazida de Tapira, MG. [S.l.]: Universidade de São Paulo. Agência de Bibliotecas e Coleções Digitais, 2024.
CAVALHEIRO PAULELLI, Ana Carolina et al. Fundão tailings dam failure in Brazil: Evidence of a population exposed to high levels of Al, As, Hg, and Ni after a human biomonitoring study. Environmental Research, v. 205, n. 112524, p. 112524, 2022. DOI: https://doi.org/10.1016/j.envres.2021.112524
COIMBRA, Keyla Thayrinne Oliveira; ALCÂNTARA, Enner; DE SOUZA FILHO, Carlos Roberto. Possible contamination of the Abrolhos reefs by Fundao dam tailings, Brazil - New constraints based on satellite data. The Science of the Total Environment, v. 733, n. 138101, p. 138101, 2020. DOI: https://doi.org/10.1016/j.scitotenv.2020.138101
DHAR, P.; THORNHILL, M.; KOTA, H. R. An Overview of Calcite Recovery by Flotation. Materials Circular Economy, v. 2, n. 1, 23 set. 2020. DOI: https://doi.org/10.1007/s42824-020-00006-y
FERREIRA, Alex Paulo de Souza et al. ROTA DE FLOTAÇÃO PARA A ROCHA FOSFÁTICA DE TAPIRA/MG. Revista Foco, v. 16, n. 12, p. e3798, 2023. DOI: https://doi.org/10.54751/revistafoco.v16n12-137
GUAN, Qingjun et al. Characterization and leaching kinetics of rare earth elements from phosphogypsum in hydrochloric acid. Minerals (Basel, Switzerland), v. 12, n. 6, p. 703, 2022. DOI: https://doi.org/10.3390/min12060703
LIANG, Haijun et al. Rare earth and phosphorus leaching from a flotation tailings of Florida phosphate rock. Minerals (Basel, Switzerland), v. 8, n. 9, p. 416, 2018. DOI: https://doi.org/10.3390/min8090416
MAUS, Victor et al. A global-scale data set of mining areas. Scientific Data, v. 7, n. 1, p. 289, 2020. DOI: https://doi.org/10.1038/s41597-020-00624-w
MOSAIC. Plano de Ação de Emergência PAEBM - Barragem BL1 Seção I. [S.l.: S.n.]. Disponível em: <https://mosaicco.com.br/ckfinder/userfiles/files/DF21-236-1-EG-RTE-0033.pdf#:~:text=para%20a%20Barragem%20BL1%20(conten%C3%A7%C3%A3o%20de%20rejeitos,de%20Minera>.
NAZARI, S. et al. Flotation of coarse particles by hydrodynamic cavitation generated in the presence of conventional reagents. Separation and Purification Technology, v. 220, p. 61–68, 2019. DOI: https://doi.org/10.1016/j.seppur.2019.03.033
PARENTE, Cláudio E. T. et al. First year after the Brumadinho tailings’ dam collapse: Spatial and seasonal variation of trace elements in sediments, fishes and macrophytes from the Paraopeba River, Brazil. Environmental Research, v. 193, n. 110526, p. 110526, 2021. DOI: https://doi.org/10.1016/j.envres.2020.110526
REIS, Angelica S. et al. Effect of bubble size on the performance flotation of fine particles of a low-grade Brazilian apatite ore. Powder Technology, v. 356, p. 884–891, 2019. DOI: https://doi.org/10.1016/j.powtec.2019.09.029
SCHÄFER, Jörg; COYNEL, Alexandra; BLANC, Gérard. Impact of metallurgy tailings in a major European fluvial-estuarine system: Trajectories and resilience over seven decades. The Science of the Total Environment, v. 805, n. 150195, p. 150195, 2022. DOI: https://doi.org/10.1016/j.scitotenv.2021.150195
SEIFELNASSR, A. A. S.; AHMED, A. A. Enrichment of Abu-Tartur phosphate ore wastes. Physicochemical Problems of Mineral Processing, [S.d.].
TEAGUE, A. J.; LOLLBACK, M. C. The beneficiation of ultrafine phosphate. Minerals Engineering, v. 27–28, p. 52–59, 2012. DOI: https://doi.org/10.1016/j.mineng.2011.12.007
VERGILIO, Cristiane Dos Santos et al. Metal concentrations and biological effects from one of the largest mining disasters in the world (Brumadinho, Minas Gerais, Brazil). Scientific Reports, v. 10, n. 1, p. 5936, 2020. DOI: https://doi.org/10.1038/s41598-020-62700-w
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Copyright (c) 2026 Thiago Duarte Figueiredo, Geovanna Rodrigues Cruz, Yago Costa Roberto, Angélica de Fátima Cruz, Francielle Câmara Nogueira, Carlos Alberto Pereira

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